Ethyl 2-oxocyclopentanecarboxylate

Ethyl 2-oxocyclopentanecarboxylate

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Ethyl 2-oxocyclopentanecarboxylate Basic information
Ethyl 2-oxocyclopentanecarboxylate
ETHYL-2-CYCLOPENTANONECARBOXYLATE;ETHYL 2-OXOCYCLOPENTANECARBOXYLATE;CYCLOPENTANONE-2-CARBOXYLIC ACID ETHYL ESTER;Ethyl 2-oxocyclopentanecarboxylate, tech., 90% 100GR;Ethyl 2-oxocyclopentanecarboxylate, tech., 90% 25GR;2-Carbethoxycyclopentanone 2-Ethoxycarbonylcyclopentanone Cyclopentanone-2-carboxylic Acid Ethyl Ester Ethyl Cyclopentanone-2-carboxylate 2-Oxocyclopentanecarboxylic Acid Ethyl Ester;Ethyl 2-oxocyclopentanecarboxylate,2-(Ethoxycarbonyl)cyclopentanone, Ethyl cyclopentanone-2-carboxylate;Ethyl-2-cyclopentanonecarboxylate 10g [611-10-9]
611-10-9
C8H12O3
156.18
210-253-0
Pharmaceutical Intermediates;BUILDING BLOCKS;C8 to C9;Carbonyl Compounds;Chemical Synthesis;Esters;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials;Organic Building Blocks
611-10-9.mol
Ethyl 2-oxocyclopentanecarboxylate Structure
 
Ethyl 2-oxocyclopentanecarboxylate Chemical Properties
102-104 degree /11 mmHg (lit.)
1.054 g/mL at 25 degree (lit.)
n20/D 1.452(lit.)
172 degree F
12.02±0.20(Predicted)
387787
JHZPNBKZPAWCJD-UHFFFAOYSA-N
0.330 (est)
611-10-9(CAS DataBase Reference)
Cyclopentanecarboxylic acid, 2-oxo-, ethyl ester(611-10-9)
 
36/37/38
23-24/25-36/37-26
3
F 10
29183000
 
2-(Ethoxycarbonyl)cyclopentanone
 
Ethyl 2-oxocyclopentanecarboxylate Usage And Synthesis
Ethyl 2-oxocyclopentanecarboxylate was used in stereoselective synthesis of (±)--spiro[4.4]nonane-1,6-diol. It was also used in the synthesis of tanikolide.
Journal of the American Chemical Society, 85, p. 207, 1963 10.1021/ja00885a021
The Journal of Organic Chemistry, 55, p. 5037, 1990 10.1021/jo00304a014
Tetrahedron Letters, 22, p. 1353, 1981 10.1016/S0040-4039(01)90316-8
Phase-transfer benzylation reaction of ethyl 2-oxocyclopentanecarboxylate with benzyl bromide in microreactor has been investigated. Ethyl 2-oxocyclopentanecarboxylate participates in cobalt (II) Schiff′s base complex catalyzed oxidation of primary and secondary alcohols.
 
Ethyl 2-oxocyclopentanecarboxylate Preparation Products And Raw materials
Tetrahydrofuran-->Acetic acid-->Sodium-->Toluene-->Potassium tert-butoxide-->Diethyl adipate-->Cyclopentanecarboxylic acid, 1-bromo-2-oxo-, ethyl ester-->1,4-Dioxaspiro[4.4]nonane-6-carboxylic acid, ethyl ester
3-Indolepropionic acid-->1-Cyclopentene-1-carboxylic acid, 2-(benzoylamino)-, ethyl ester-->Naphth[2,3-b]oxiren-2(1aH)-one, 7,7a-dihydro-7-hydroxy-1a,7-dimethyl--->2-CYCLOPENTANONE CARBOXYLATE-->3-oxo-2-pentylcyclopentaneacetic acid-->7-Hydroxy-2,3-dihydro-1H-cyclopenta[c]chromen-4-one-->MDL-29951-->

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